题目：

Hierarchical Self-assembly of Organic Heterostructure Nanowires

作者：

Ming-Peng Zhuo¹, Jun-Jie Wu¹, Xue-Dong Wang^1,*, Yi-Chen Tao¹, Yi Yuan¹, Liang-Sheng Liao^1,2,*

单位：

¹Institute of Functional Nano & Soft Materials (FUNSOM), Collaborative Innovation Center of Suzhou Nanoscience and Technology, Soochow University, 199 Ren-AiRoad, Suzhou 215123, China.

²Institute of Organic Optoelectronics, JITRI, Wujiang, Suzhou, Jiangsu 215211, P. R. China.

摘要：

Organic heterostructures (OHSs) integrating the intrinsic heterostructure characters as well as the organic semiconductor properties have attracted intensive attention in material chemistry. However, the precise bottom-up synthesis of OHSs is still challenging owing to the general occurrence of homogeneous-nucleation and the difficult manipulation of noncovalent interactions. Herein, we present the rational synthesis of the longitudinally/horizontally epitaxial growth of one-dimensional OHSs including triblock and core/shell nanowires with quantitatively-manipulated microstructure via a hierarchical self-assembly method by regulating the noncovalent interactions: hydrogen bond (−15.66 kcal mol⁻¹) > halogen bond (−4.90 kcal mol⁻¹) > π-π interaction (−0.09 kcal mol⁻¹). In the facet-selective epitaxial growth strategy, the lattice-matching and the surface-interface energy balance respectively facilitate the realization of triblock and core/shell heterostructures. This hierarchical self-assembly approach opens up avenues to the fine synthesis of OHSs. We foresee application possibilities in integrated optoelectronics, such as the nanoscale multiple input/out optical logic gate with high-fidelity signal.

影响因子：

12.353

分区情况：

一区

链接：

https://www.nature.com/articles/s41467-019-11731-7

责任编辑：朱文昌