摘要：

Large-area electronics have a natural eagerness to manufacture electronic devices with high scale-cost-performance metrics for emerging applications, spanning from the Internet of Things to flexible and wearable electronics. Printing technologies facilitate high-throughput production of reliable, stable, and cost-effective devices, but the suboptimal electronic quality of solution-printed semiconducting materials has constrained device performance across broader application spaces. Here, fully printed, monolithically integrated, large-scale thin-film transistor (TFT) arrays featuring high-quality organic single-crystalline films as device channels are reported. This breakthrough is achieved through sophisticated fluid dynamic engineering across multiple and uneven heterointerfaces. These fully-printed TFTs unlock previously inaccessible theoretic performance boundaries, delivering exceptional electrical performance with a near-ideal subthreshold swing of 59.4 mV dec⁻¹, a record-high mobility of 13.8 cm2 V⁻¹ s⁻¹, and low operation voltages. This approach through large-scale production is further validated, successfully fabricating 2500 organic thin-film transistors (OTFTs) over 30 cm² area with a remarkable device yield exceeding 99.92%. Furthermore, the versatility of this fully printed organic TFT array as an active matrix integrated multisensory platform is showcased, signifying a significant advancement in printed electronics.

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