康振辉教授课题组在Catal. Sci. Technol.上发表论文
Air activation by a metal-free photocatalyst for“totally-green” hydrocarbon selective oxidation | |
作者: | Yalin Zhang, Lulu Hu, Cheng Zhu, Juan Liu, Hui Huang,* Yang Liu* and Zhenhui Kang* |
单位: | Jiangsu Key Laboratory for Carbon-basedFunctional Materials and DevicesInstitute of Functional Nano and SoftMaterials (FUNSOM) Soochow UniversitySuzhou 215123, China |
摘要: | We show the fabrication and photocatalytic properties of triazine-based carbon nitride (polytriazine imide, PTI). The obtained PTI, with higher crystallinity and a triazine structure unit, is sufficiently characterised by X-ray powder diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and solid state NMR. We demonstrate that PTI is an efficient photocatalyst for activation in air and water, bywhich, the total green cyclohexane selective oxidation (5.81% conversion and over 99.9% selectivity tocyclohexanone) can be realized only using air and water without any other oxidants, initiators |
影响因子: | 5.287 |
分区情况: | 1区 |
链接: | http://pubs.rsc.org/en/content/articlelanding/2016/cy/c6cy01066k#!divAbstract |