康振辉教授课题组在 RSC Adv上发表论文

题目：

Coordinate-polymerized organic ligand towards an efficient catalyst for selective hydrocarbon oxidation

作者：

Kaixuan Li,‡ Hailiang Hu,‡ Beibei Liu, Xiaoling Lin, Hui Huang,* Yang Liu* and Zhenhui Kang*

单位：

Institute of Functional Nano & So Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou, Jiangsu 215123, China. E-mail: zhkang@suda.edu.cn

摘要：

Here we show catalyst design based on an isoxazole derivative via a coordinate-polymerized strategy. Three new coordination polymers, [Co(bpp)(mpca)₂](1),[Zn(bpp)(mpca)₂](2),and[Cd(bpp)(mpca)₂](3) [bpp=1,3-bis(4-pyridyl)propane,mpca=5-methyl-3-phenylisoxazole-4-carboxylic acid], have been synthesized under hydrothermal conditions. Single crystal X-ray diffraction ****ysis reveals that, compounds 1–3 exhibit similar wave-like chains, with mpca functioning as pendant phenyl-isoxazole arms. Catalytic experiments show that all three compounds can be used as efficient heterogeneous catalysts for the selective oxidation of cyclooctene.

影响因子：

3.289

分区情况：

2区  

链接：  

http://pubs.rsc.org/en/content/articlelanding/2016/ra/c6ra12422d#!divAbstract