康振辉教授课题组在Dalton Trans.上发表论文
A spherical deca-vanadophosphate covalentassembled all-inorganic open framework | |
作者: | Hailiang Hu, Zhenyu Guo, Kaixuan Li, Xiaoling Lin, Yang Liu* and Zhenhui Kang* |
单位: | Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou, Jiangsu 215123, People’s Republic of China. E-mail: zhkang@suda.edu.cn |
摘要: | Through covalent connection of phosphate groups, an all-inorganic open framework, [NH4]9[P4V10O34]1.5·3H2O (1), has been prepared by a hydrothermal reduction–condensation method. It is built from a vanadophosphate (VPO) unit of [P4V10O34] 6−, which represents a rare example of a spherical {V10-type} structure among the VPO family. Further studies also demonstrate that compound 1 is an n-type semiconductor. |
影响因子: | 4.177 |
分区情况: | 2区 |
链接: | http://pubs.rsc.org/en/content/articlelanding/2017/dt/c6dt03850f#!divAbstract |