康振辉教授课题组在Nature Communications上发表文章

康振辉教授课题组在Nature Communications上发表文章

题目：

A Co₃O₄-CDots-C₃N₄ three component electrocatalyst design concept for efficient and tunable CO₂ reduction to syngas

作者：

Sijie Guo¹, Siqi Zhao¹, Xiuqin Wu¹, Hao Li¹, Yunjie Zhou¹, Cheng Zhu¹, Nianjun Yang², Xin Jiang², Jin Gao¹, Liang Bai¹, Yang Liu¹, Yeshayahu Lifshitz¹,³, Shuit-Tong Lee¹ & Zhenhui Kang¹

单位：

1 Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano & Soft Materials (FUNSOM), Soochow University, 199 Ren’ai Road, Suzhou, 215123 Jiangsu, China.

2 Institute of Materials Engineering, University of Siegen, 57076 Siegen, Germany.

3 Department of Materials Science and Engineering, Technion, Israel Institute of Technology, Haifa 3200003, Israel.

摘要：

Syngas, a CO and H₂ mixture mostly generated from non-renewable fossil fuels, is an essential feedstock for production of liquid fuels. Electrochemical reduction of CO₂ and H⁺/H₂O is an alternative renewable route to produce syngas. Here we introduce the concept of coupling a hydrogen evolution reaction (HER) catalyst with a CDots/C₃N₄ composite (a CO₂ reduction catalyst) to achieve a cheap, stable, selective, and efficient route for tunable syngas production. Co₃O₄, MoS₂, Au, and Pt serve as the HER component. The Co₃O₄-CDots-C₃N₄ electrocatalyst is found the most efficient among the combinations studied. The H₂/CO ratio

of the produced syngas is tunable from 0.07:1 to 4:1 by controlling the potential. This catalyst is highly stable for syngas generation (over 100 h) with no other products besides CO and H₂. Insight into the mechani**s balancing between CO₂ reduction and H₂ evolution when applying the HER-CDots-C₃N₄ catalyst concept is provided.

影响因子：

12.124

分区情况：

一区

链接：

https://www.nature.com/articles/s41467-017-01893-7.pdf