我组曹静静在Journal of Materials Chemistry A上发表论文

题目：

Phosphorus-doped porous carbon nitride for efficient sole production of hydrogen peroxide via photocatalytic water splitting with a two-channel pathway

作者：

Jingjing Cao,‡ Hui Wang,‡ Yajie Zhao, Yan Liu, Qingyao Wu, Hui Huang, * Mingwang Shao, * Yang Liu* and Zhenhui Kang

单位：

 †Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano & Soft Materials

(FUNSOM), Soochow University, 199 Ren’ai Road, Suzhou 215123, Jiangsu, People’s Republic of China

摘要：

The production of hydrogen peroxide (H₂O₂) by photocatalytic water splitting has attracted much attention due to the wide application of H₂O₂ as a multi-functional chemical. Most of the present photocatalysts require sacrificial agents and/or noble metal cocatalysts. Herein, we report that phosphorus-doped porous carbon nitride (CPN), as a metal-free photocatalyst, achieves the photocatalytic water splitting via a two-channel pathway (water oxidation reaction and oxygen reduction reaction) with high H₂O₂ yield of 1968 mmol g^-1 h^-1 (highest yield in current records without sacrificial agent) under room temperature and normal pressure without sacrificial agent and cocatalyst. The quantum efficiency of the sole production of H₂O₂ was measured to be 1.57% under wavelength l ¼ 420 nm and the solar energy conversion efficiency was determined to be 0.43%. In the present reaction system, the concentration of H₂O₂ can be up to 0.171% (wt%) in a one-batch reaction using 80 mg CPN catalyst (in 15 mL oxygen saturated H₂O) after 36 h under visible light illumination. H₂O₂ obtained by this metal-free catalyst without adding a sacrificial agent is more conducive to subsequent purification in industrial production

影响因子：

11.301

分区情况：

1区

链接：  

https://doi.org/10.1039/C9TA13929J