我组吴清瑶在Nature Communications上发表论文

题目：

A metal-free photocatalyst for highly efficient hydrogen peroxide photoproduction in real seawater

作者：

Qingyao Wu¹, Jingjing Cao¹, Xiao Wang¹, Yan Liu¹, Yajie Zhao¹, Hui Wang¹, Yang Liu¹, Hui Huang¹, Fan Liao¹,

Mingwang Shao¹ & Zhenghui Kang ^1,2

单位：

1 Institute of Functional Nano and Soft Materials Laboratory (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, 215123 Suzhou, PR China.

2 Macau Institute of Materials Science and Engineering, Macau University of Science and Technology, Macau, China.

摘要：

Artificial photosynthesis of H₂O₂ from H₂O and O₂, as a spotless method, has aroused widespread interest. Up to date, most photocatalysts still suffer from serious salt-deactivated effects with huge consumption of photogenerated charges, which severely limit their wide application. Herein, by using a phenolic condensation approach, carbon dots, organic dye molecule procyanidins and 4-methoxybenzaldehyde are composed into a metal-free photocatalyst for the photosynthetic production of H₂O₂ in seawater. This catalyst exhibits high photocatalytic ability to produce H₂O₂ with the yield of 1776 μmol g⁻¹h⁻¹ (λ ≥ 420 nm; 34.8mWcm⁻²) in real seawater, about 4.8 times higher than the pure polymer. Combining with in-situ photoelectrochemical and transient photovoltage ****ysis, the active site and the catalytic mechani** of this composite catalyst in seawater are also clearly clarified. This work opens up an avenue for a highly efficient and practical, available catalyst for H₂O₂ photoproduction in real seawater.

影响因子：

12.121

分区情况：

1区

链接：  

https://www.nature.com/articles/s41467-021-21490-z