题目：

Copper Salts Doped Spiro-OMeTAD for High-Performance Perovskite Solar Cells

作者：

Meng Li¹, Zhao-Kui Wang,¹* Ying-Guo Yang², Yun Hu¹, Shang-Lei Feng², Jin-Miao Wang¹, Xing-Yu Gao², and Liang-Sheng Liao¹*

单位：

¹Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano & Soft Materials (FUNSOM), Soochow University, Suzhou, Jiangsu, 215123, P. R. China.

²Shanghai Synchrotron Radiation Facility Shanghai Institute of Applied Physics Chinese Academy of Sciences Shanghai 201204, China.

摘要：

The development of effective and stable hole transporting materials (HTMs) is very important for achieving high-performance planar perovskite solar cells (PSCs). Herein, copper salts (cuprous thiocyanate (CuSCN) or cuprous iodide (CuI)) doped 2,2,7,7-tetrakis(N,N-di-p-methoxyphenylamine)-9,9-spirobifluorene (spiro-OMeTAD) based on a solution processing as the HTM in PSCs is demonstrated. The incorporation of CuSCN (or CuI) realizes a p-type doping with efficient charge transfer complex, which results in improved film conductivity and hole mobility in spiro-OMeTAD:CuSCN (or CuI) composite films. As a result, the PCE is largely improved from 14.82% to 18.02% due to obvious enhancements in the cell parameters of short-circuit current density and fill factor. Besides the HTM role, the composite film can suppress the film aggregation and crystallization of spiro-OMeTAD films with reduced pinholes and voids, which slows down the perovskite decomposition by avoiding the moisture infiltration to some extent. The finding in this work provides a simple method to improve the efficiency and stability of planar perovskite solar cells.

影响因子：

16.146

分区情况：

一区

链接：

http://onlinelibrary.wiley.com/wol1/doi/10.1002/aenm.201601156/full  

（责任编辑：向丹婷 联系方式：dtxiang@suda.edu.cn）