题目：

Supported Cobalt Polyphthalocyanine for High-Performance ElectroCatalytic CO₂ Reduction

作者：

Na Han^{1, 5}, Yu Wang ^{2, 5} , Lu Ma³ , Jianguo Wen⁴ , Jing   Li ⁴ , Hechuang Zheng¹ , Kaiqi Nie¹ , Xinxia   Wang¹ , Feipeng Zhao ¹,Yafei Li ^2, * , Jian Fan¹，Jun Zhong¹, Tianpin Wu³,   Dean J. Miller ⁴, Jun Lu ^3, *, Shuit-Tong Lee¹,   and Yanguang Li^{1, 6,} *

单位：

¹Institute of Functional Nano & Soft  Materials (FUNSOM), Collaborative Innovation Center of Suzhou Nanoscience and Technology, Soochow University, 199 Ren-AiRoad, Suzhou 215123, China.

²College of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, China.

³Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, IL 60439, USA.

⁴Center for Nanoscale Materials, Argonne National Laboratory, Lemont, IL   60439, USA.

⁵These authors contributed equally

⁶Lead Contact

摘要：

Electrochemical reduction of CO₂ represents a possible solution for transforming atmospheric CO₂ to value-added chemicals such as CO or hydrocarbons, but so far it has been hampered by the lack of suitable electrocatalysts. In this work, we design a   type of organic-inorganic hybrid material by template-directed polymerization   of cobalt phthalocyanine on carbon nanotubes for a high-performance CO₂ reduction reaction. Compared with molecular phthalocyanines, the polymeric form of phthalocyanines supported on the conductive scaffold exhibits an enlarged electrochemically active surface area and improved physical and chemical robustness. Experimental results show that our hybrid   electrocatalyst can selectively reduce CO₂ to CO with a large faradic efficiency (~90%), exceptional turnover frequency (4,900 hr^-1   at η = 0.5 V), and excellent long-term durability. These metrics are superior to those of most of its organic or inorganic competitors. Its high electrocatalytic activity is also supported by density functional theory calculations.

影响因子：

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分区情况：

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链接：

http://dx.doi.org/10.1016/j.chempr.2017.08.002