题目：

Air activation by a metal-free photocatalyst for “totally-green” hydrocarbon selective oxidation

作者：

Yalin Zhang, Lulu Hu, Cheng Zhu, Juan Liu, Hui Huang,* Yang Liu* and Zhenhui Kang*

单位：

Jiangsu Key Laboratory for Carbon-based Functional Materials＆  Devices, Institute of Functional Nano ＆Soft Materials (FUNSOM),199Ren'ai Road, Suzhou, 215123, Jiangsu, PR China.

摘要：

We show the fabrication and photocatalytic properties of triazine-based carbon nitride (polytriazine imide, PTI). The obtained PTI, with higher crystallinity and a triazine structure unit, is sufficiently characterised by X-ray powder diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and solid state NMR. We demonstrate that PTI is an efficient photocatalyst for activation in air and water, by which, the total green cyclohexane selective oxidation (5.81% conversion and over 99.9% selectivity to cyclohexanone) can be realized only using air and water without any other oxidants, initiators and solvents.

影响因子：

5.287

分区情况：

二区

链接： 

http://pubs.rsc.org/en/content/articlelanding/2016/cy/c6cy01066k#!divAbstract