题目：

A spherical deca-vanadophosphate covalent assembled all-inorganic open framework

作者：

Hailiang Hu, Zhenyu Guo, Kaixuan Li, Xiaoling Lin, Yang Liu* and Zhenhui Kang*

单位：

Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou, Jiangsu 215123, People’s Republic of China.

摘要：

Through covalent connection of phosphate groups, an all-inorganic open framework, [NH₄]₉[P₄V₁₀O₃₄]_1.5・3H₂O (1), has been prepared by a hydrothermal reduction�condensation method. It is built from a vanadophosphate (VPO) unit of [P₄V₁₀O₃₄] ⁶⁻, which represents a rare example of a spherical {V₁₀-type} structure among the VPO family. Further studies also demonstrate that compound 1 is an n-type semiconductor.

影响因子：

4.177

分区情况：

2区

链接： 

http://pubs.rsc.org/en/content/articlelanding/2017/dt/c6dt03850f#!divAbstract

责任编辑：向丹婷 联系方式：dtxiang@suda.edu.cn