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康振辉教授课题组在Applied Catalysis B: Environmental上发表论文
发布时间:2017-10-01 点击:1105

题目:

Carbon Dots Decorated the Exposing High-Reactive (111) Facets CoO Octahedrons with Enhanced Photocatalytic Activity and Stability for Tetracycline Degradation under Visible Light Irradiation


作者:

Weilong Shi,ab Feng Guo,ac Huibo Wang,a Mumei Han,a Hao Li,a Songliu Yuan,b HuiHuang,a*, Yang Liua*, Zhenhui Kanga*


单位:

aJiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano & Soft Materials(FUNSOM), Soochow University, 199 Ren'ai Road, Suzhou, 215123, Jiangsu, PR China.

bSchool of Physics, Huazhong University of Science and Technology, Wuhan 430074, P.R. China;

cKey Laboratory of Subsurface Hydrology and Ecological Effects in Arid Region, Ministry of Education, School ofEnvironmental Science and Engineering, Chang’an University, Xi’an 710064, P.R. China;


摘要:

Octahedral CoO with exposed high-reactive (111) facets holds a promising noble-metal-free material in the photocatalysis. However, the (111) facet is usually unstable and easily deactivated during the photocatalytic process as the result of its poloar catastrophe. In this work, carbon dots (CDs) as co-catalyst modified and stabilized the (111) facets of CoO octahedrons (CDs-CoO) were prepared by one-step solvothermal method. The desired CDs-CoO shows the excellent photocatalytic activity and well stability. Meanwhile, the CDs-CoO (5 wt.%) composite exhibits the highest photocatalytic activity for degradation of tetracycline (87%, 60 min), and presents remarkable photostability with only around 5% loss after five successive cycles (5 h). This enhanced photocatalytic activity and outstanding stability in CDs-CoO composites could be ascribed to several merits of CDs that not only improve charge separation efficiency but also strengthen the interaction between CDs and high-reactive (111) facets of CoO octahedrons.


影响因子:

9.446


分区情况:

一区


链接:

http://www.sciencedirect.com/science/article/pii/S0926337317306598



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