题目：

Indirect Control of Donor/Acceptor Interactions for Highly Efficient Space-Confined Thermally Activated Delayed Fluorescence Emitters

作者：

Zi-Qi Feng¹, Sheng-Yi Yang¹, Fan-Cheng Kong¹, Yang-Kun Qu¹, Xin-Yue Meng¹, You-Jun Yu¹, Dong-Ying Zhou¹*, Zuo-Quan Jiang¹*, and Liang-Sheng Liao^1,2*

单位：

¹Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou, Jiangsu 215123, China

²Macao Institute of Materials Science and Engineering, Macau University of Science and Technology, Macau, Taipa 999078, China.

摘要：

Conformational engineering is essential to further reinforce the luminescent properties of thermally activated delayed fluorescence (TADF) materials featuring through-space charge transfer (TSCT) characteristics. Herein, two TSCT-TADF emitters (8MeDM-B and 8FDM-B) with the methyl and fluorine moieties substituted at the C8 site of the rigid spiro-fluorene bridge is reported. Derivation of the C8 site is first proposed to control the molecular configuration with the ability to indirectly tune the intramolecular interaction between donor and acceptor groups. As a result, 8MeDM-B and 8FDM-B both present small singlet-triplet energy gaps, fast reverse intersystem crossing rates, and high photoluminescence quantum yields. Interestingly, the smaller fluorine atom not the bigger methyl group exhibits more evident electrostatic repulsive force onto the central donor and thus rectifies the central spiro structure. Consequently, the high external quantum efficiency values of 28.8% and 31.7% for 8MeDM-B and 8FDM-B-based electroluminescence devices are achieved, respectively. This study offers a measure for enhancing TSCT-TADF emitters without directly modifying the donor or acceptor.

影响因子：

19.924

分区情况：

一区

链接：

https://doi.org/10.1002/adfm.202209708