题目：

Photochemical Shield Enabling Highly Efficient Perovskite Photovoltaics

作者：

Run-Jun Jin¹, Yan-Hui Lou², Lei Huang¹, Kai-Li Wang¹, Chun-Hao Chen¹, Jing Chen¹, Fan Hu¹, and Zhao-Kui Wang¹

单位：

¹Institute of Functional Nano and Soft Materials (FUNSOM), Soochow University, Suzhou, China.

²Institute for Energy and Materials Innovations, Soochow University, Suzhou, China.

摘要：

Oxygen is difficult to be physically removed. Oxygen will be excited by light to form free radicals which further attack the lattice of perovskite. The stabilization of α-FAPbI3 against δ-FAPbI3 is the key to optimize perovskite solar cells. Herein, the simple molecule, benzaldehyde (BAH) is adopted. The photochemical shield will be established in perovskite layer. Moreover, heterogeneous nucleation induced by BAH enhances the crystallization of α-FAPbI3. Consequently, the stability of device is improved significantly. The target device maintains 95% of original power conversion efficiency after 1500 h under air conditions and light-emitting diode light. The power conversion efficiency increases from 23.21% of pristine device to 24.82% of target device.

影响因子：

32.086

分区情况：

一区

链接：

https://onlinelibrary.wiley.com/doi/full/10.1002/adma.202313154