作者：

Xueqi Wu^1,2#, Xin Li^1,2#, Huanyu Zhang^1#, Yitong Liu¹, Yige Peng¹, Yi Ji¹, Yurou Zhang³, Zewu Feng^1,3, Chenghao Ge¹, Yanbo Wang^1,3, Yansen Guo^1,3, Hailong Huang^1,3, Shuilong Kang¹, Yuan Fang¹, Jing Chen⁴, Weichang Zhou⁴, Dongsheng Tang⁴, Yu Zeng¹, Chaopeng Huang³, Zhongyao Jiang⁵, Haifeng Gao⁵, Qiang Zhang⁵, Jingsong Sun³, Youyong Li¹*, Xiao-Hong Zhang²*, Jun Peng^1,2,3*

单位：

¹State Key Laboratory of Bioinspired Interfacial Materials Science, Institute of Functional Nano & Soft Materials (FUNSOM), Soochow University, Suzhou, China. 

²Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory of Advanced Negative Carbon Technologies, Soochow University, Suzhou, China.

³Zhejiang Baima Lake Lab Co Ltd, Hangzhou, China.

⁴School of Physics and Electronics, Key Laboratory of Low-dimensional Quantum Structures and Quantum Control of Ministry of Education, Hunan Normal University, Changsha, China.

⁵China Electric Power Research Institute Co., Ltd., State Grid Corporation of China, Beijing, China.

摘要：

The rapid development of self-assembled monolayers (SAMs) has been instrumental in advancing the power conversion efficiency (PCE) of inverted perovskite solar cells (PSCs) to exceed 26%. However, benchmark SAMs are limited by stochastic assembly kinetics and weak interfacial coupling with the perovskite, which induce severe interfacial recombination and compromise device stability. Here, we developed an amino acid hydrochloride (AAH)-mediated SAM to construct high-performance PSCs. By systematically modulating the AAH alkyl spacer length, we elucidate an optimal steric profile that balances thermodynamic anchoring with kinetic intermolecular organization. This optimized AAH-mediated SAM exhibits enhanced coverage, uniformity, and molecular packing density, stabilizing the interface via reduced defect density and refined energy level alignment. Moreover, the AAH terminal ammonium (–NH₃⁺Cl^-) moieties establish a chemical bridge with the perovskite, effectively passivating interfacial defects and promoting stress-free crystallization. Consequently, the devices based on AAH-mediated SAMs delivered a champion PCE of 26.87% (certified at 26.33%) on a 0.058 cm² area and 25.90% on a 1-cm² area. Encapsulated device exhibited excellent operational stability, retaining over 97.3% of its initial efficiency after 1100 h of continuous operation at the maximum power point in air.

影响因子：

26

分区情况：

一区

链接：

https://doi.org/10.1002/aenm.70925